李世清，男，漢族，1989年9月出生于湖南省邵陽(yáng)市，理學(xué)博士，2017年6月進(jìn)入桂林理工大學(xué)化學(xué)與生物工程學(xué)院，從事教學(xué)與科研工作。

一、教育背景： 

2008/9-2012/6 云南大學(xué)化學(xué)科學(xué)與工程學(xué)院，化學(xué)，本科（畢業(yè)論文導(dǎo)師：林軍）

2012/9-2014/6 四川大學(xué)，化學(xué)學(xué)院，有機(jī)化學(xué)，碩士（導(dǎo)師：高戈/游勁松） 

2014/9-2017/6 四川大學(xué)，化學(xué)學(xué)院，有機(jī)化學(xué)，博士（導(dǎo)師：高戈/游勁松）

2017/6-2021/11 桂林理工大學(xué)，化學(xué)與生物工程學(xué)院，講師

2022/9-2023/7 南開(kāi)大學(xué)，化學(xué)學(xué)院，訪(fǎng)問(wèn)學(xué)者（合作導(dǎo)師：朱守非/趙東兵）

2021/11至今 桂林理工大學(xué)，化學(xué)與生物工程學(xué)院，副教授

二、主講課程：

《有機(jī)化學(xué)》、《大學(xué)化學(xué)》、《普通化學(xué)》、《無(wú)機(jī)化學(xué)》

三、研究方向： 

有機(jī)合成方法學(xué)（新試劑與新反應(yīng)）、C-H鍵功能化/串聯(lián)反應(yīng)與機(jī)制研究、高價(jià)碘化學(xué)、有機(jī)光電材料和藥物分子的設(shè)計(jì)與合成。課題組主頁(yè)：https://www.x-mol.com/groups/LI_Shiqing-GLUT

四、主持的科研項(xiàng)目：

（1）國(guó)家自然科學(xué)基金，地區(qū)基金項(xiàng)目，22261013，環(huán)狀酸酐介導(dǎo)無(wú)痕策略促使無(wú)機(jī)肼轉(zhuǎn)化成有機(jī)含氮氮雙鍵化合物研究，2023.01-2026.12，33萬(wàn)。

（2）國(guó)家自然科學(xué)基金，青年基金項(xiàng)目，22001049，C-H活化/聯(lián)導(dǎo)向基策略一步構(gòu)筑（軸手性）聯(lián)異喹啉衍生物及其金屬螯合物的應(yīng)用，2021.01-2023.12，24萬(wàn)。

（3）廣西自然科學(xué)基金，青年基金項(xiàng)目，2020GXNSFBA297003，2021.01-2023.12，8萬(wàn)。

（4）廣西自然科學(xué)基金聯(lián)合資助培育項(xiàng)目，2018GXNSFAA294037，2019.01-2021.04，20萬(wàn)。

（5）廣西科技基地和人才專(zhuān)項(xiàng)，AD19245095，2020.01-2022.12，10萬(wàn)。

五、代表性成果（論文）

2023

[24] Y. Yang, R. Xie, Y. Wang, P. Zhu, J. Wang, S. Li*. Efficient synthesis of benzo[c]cinnolines and azoarenes via dual C?N coupling of phthalhydrazide and trivalent halogen reagents. Org. Chem. Front. 2023, DOI: 10.1039/D3QO00391D. (SCI一區(qū))

 

[23] C. Wen, Y. Wang, Y. Yang, Y.-N. Tian, J. Wang, S. Li*. Hydrazone-oxime Selectively Directed Redox-Neutral [4+2] Annulations Cascade with Alkynes and Iodonium Ylides to Build 1,1′-Biisoquinoline Mono?N?oxides. Org. Lett. 2023, 25, 2616–2621. (SCI一區(qū))

[22] R. Xie,^‖ Y. Xiao,^‖ Y. Wang, Z.-W. Xu, N. Tian, S. Li*, M.-H. Zeng*. Hydrazine?Halogen Exchange Strategy Toward N=N-Containing Compounds and Process Tracking for Mechanistic Insight. Org. Lett. 2023, 14, 2415–2419. (^‖Equal contribution) (SCI一區(qū)，封面文章)

    

[21] Y. Wang, Y.-N. Tian, S. Ren, R. Zhu, B. Huang, Y. Wen, S. Li*. Metal-free homo-/cross-anion–cation coupling of cyclic diaryl λ³-bromanes. Org. Chem. Front. 2023, 10, 793–798. (SCI一區(qū))

[20] Y.-N. Tian, S. Lv, L. Huang, C. Wen, Y. Yang, X. Kong, Q. Zhu*, S. Li*. Experimental and computational studies on rhodium-catalyzed C4(5)_aryl?H activation/annulations of imidazoles with alkynes: facile synthesis of six types of N-heterocycles. Org. Chem. Front. 2023, 10, 83?91. (SCI一區(qū))

 

2022

 

[19] L. Huang, Y.-N. Tian, S. Ren, J. Wang, Y. Xiao, Q. Zhu*, S. Li*. Palladium-catalysed dual ring-opening [3 + 4] annulation of isatoic anhydrides with cyclic iodoniums to build tribenzo[b,d,f]azepines and a mechanistic DFT study. Org. Chem. Front. 2022, 9, 6259-6264. (SCI一區(qū))

 

[18] S. Lv, Y.-N. Tian, Y. Yang, C. Wen, S. Li*. Rh(III)-Catalyzed One-Pot Three-Component Diannulation of Benzils, Ammonium Acetate, and Alkynes to Build 1,1′-Biisoquinolines. J. Org. Chem. 2022, 87, 16019?16025. (SCI二區(qū))

 

[17] L. Huang?, R. Xie?, C. Wen, Y. Yang, Y. Wang, S. Ren, B. Huang, S. Li*. Decarbonylative /decarboxylative [4 + 2] annulation of phthalic anhydrides and cyclic iodoniums towards triphenylenes. Org. Biomol. Chem. 2022, 20, 3913–3916. (? Equal contribution, Highlighted by Synfacts) (SCI三區(qū))

[16] Y. Wang?, Y. Yu?(本科生), R. Xie, Y.-N. Tian, L. Huang, S. Lv, X. Meng, X. Kong, S. Li*. Cu/Fe-mediated N(sp²)-arylation/alkenylation of pyridines with aryl-/alkenylboronic acids to yield versatile cationic materials. New J. Chem. 2022, 46, 2320–2325. (? Equal contribution) (SCI三區(qū))

2021

[15] Y. Wang (推免至華中師范大學(xué)讀博), R. Xie, L. Huang, Y.-N. Tian, S. Lv, X. Kong, S. Li*. Divergent synthesis of unsymmetrical azobenzenes via Cu-catalyzed C–N coupling. Org. Chem. Front. 2021, 8, 5962–5967. (SCI一區(qū))

 

[14] X. Kong, R. Luo, H. Gong, D. Chen, S. Yang, S. Li*, G. Wang*, Z. He*. Discotic liquid crystals with aggregation-induced emission properties based on tetraphenylethylene and triphenylene derivatives. Mol. Cryst. Liq. Cryst. 2021, 724, 26?37.

2020

[13] S. Li*, H. Lv, R. Xie, X. Ye, X. Kong*. The C?H Activation/Bidirecting Group Strategy for Selective Direct Synthesis of Diverse 1,1′-Biisoquinolines. Org. Lett. 2020, 22, 4207?4212. (SCI一區(qū))

 

[12] R. Xie,^# H. Lv,^# X. Ye, X. Kong*, S. Li*. Cu-Catalyzed tandem N-arylation of phthalhydrazides with cyclic iodoniums to yield dihydrobenzo[c]cinnolines. Org. Biomol. Chem. 2020, 18, 4824?4830. (^# Equal contribution) (SCI三區(qū))

[11] Y. Yu (本科生), H. Lv, S. Li*. The C–H functionalization of organic cations: an interesting and fresh journey. Org. Biomol. Chem. 2020, 18, 8810–8826. (SCI 三區(qū))

2019 

[10] S. Li*, H. Lv (推免至華東師范大學(xué)讀博), Y. Yu, X. Ye, B. Li, S. Yang, Y. Mo, X. Kong*. Domino N-/C- or N-/N-/C-arylation of imidazoles to yield polyaryl imidazolium salts via atom-economical use of diaryliodonium salts. Chem. Commun. 2019, 55, 11267?11270. (SCI一區(qū))

 

2018以前

[9] S. Li, J. Tang, Y. Zhao, R. Jiang, T. Wang, G. Gao*, J. You*, Cu-Catalyzed Controllable C?H Mono-/Di-/Triarylations of Imidazolium Salts for Ionic Functional Materials, Chem. Commun. 2017, 53, 3489?3492.

[8] S. Li, F. Yang, T. Lv, J. Lan, Ge Gao*, J, You*, Synthesis of unsymmetrical imidazolium salts by direct quaternization of N-substituted imidazoles using arylboronic acids, Chem. Commun. 2014, 50, 3941?3943.

[7] Y. Zhao, S. Li, X. Zheng, J. Tang, Z. She, G. Gao*, J. You*, Rh/Cu-Catalyzed Cascade [4+2] Vinylic C?H O-Annulation and Ring Contraction of a-Aryl Enones with Alkynes in Air, Angew. Chem. Int. Ed. 2017, 56, 4286?4289. （國(guó)際頂級(jí)期刊）

[6] J. Tang, S. Li, Z. Liu, Y. Zhao, Z. She, V.s D. Kadam, G. Gao*, J. Lan, J. You*，Cascade C?H Annulation of Aldoximes with Alkynes Using O2 as the Sole Oxidant: One-Pot Access to Multisubstituted Protoberberine Skeletons, Org. Lett. 2017, 19, 604-607.

[5] X. Li, S. Li, G. Gao, D. Wu, J. Lan*, R. Wang*, J. You*，High Performance Ruthenium Sensitizers Containing Imidazoliums as Counterions for the Efficient Dye-Sensitization in Water, ChemSusChem. 2017, 10, 2914?29121. 

[4] H. Zhou, Y., Zhao, G. Gao*, S. Li, J. Lan, J. You*, Highly Selective Fluorescent Recognition of Sulfate in Water by Two Rigid Tetrakisimidazolium Macrocycles with Peripheral Chains, J. Am. Chem. Soc. 2013, 135, 14908?14911. （國(guó)際頂級(jí)期刊）

[3] Z. He, X. Qi, S. Li, Y. Zhao, G. Gao*, Y. Lan*, Y. Wu, J. Lan, J. You*, Transition-Metal-Free Formal Decarboxylative Coupling of α-Oxocarboxylates with α-Bromoketones under Neutral Conditions: A Simple Access to 1,3-Diketones, Angew. Chem. Int. Ed. 2015, 54, 855?859.（國(guó)際頂級(jí)期刊）

[2] Y. Zhao, Z. He, S. Li, J. Tang, G. Gao*, J. Lan, J. You*, An Air-stable Half-sandwich Ru^II complex as an efficient Catalyst for [3+2] Annulation of 2-Arylcyclo-2-enones with Alkynes, Chem. Commun. 2016, 52, 4613?4616.

[1] Z. He, X. Qi, Z. She, Y. Zhao, S. Li, J. Tang, G. Gao*, Y. Lan*, J. You*, Room-Temperature Coupling/Decarboxylation Reaction of α?Oxocarboxylates with α?Bromoketones: Solvent-Controlled Regioselectivity for 1,2- and 1,3-Diketones, J. Org. Chem. 2017, 82, 1403?1411.

六、授權(quán)發(fā)明專(zhuān)利

[1] 李世清，李永樹(shù)，梁霞靜，劉運(yùn)烽，陳紫園，潘梅玲. 聯(lián)苯基橋聯(lián)雙苯并咪唑鎓的制備方法及其應(yīng)用，中國(guó)發(fā)明專(zhuān)利，ZL 201811538437.5，2022年3月22日授權(quán)。

[2] 李世清，呂洪旭，余雨，葉秀青，黎柏松，楊松明，莫炎儒. 一種由二芳基碘鎓鹽與咪唑合成五芳基咪唑鎓鹽的方法，中國(guó)發(fā)明專(zhuān)利，ZL 201910658316.2，2022年8月9日授權(quán)。

七、招生與聯(lián)系方式

招生：招收化學(xué)、化學(xué)工程與技術(shù)、材料與化工等專(zhuān)業(yè)一志愿以及調(diào)劑錄取的碩士研究生，歡迎有機(jī)化學(xué)愛(ài)好者報(bào)考本課題組！也歡迎喜歡科研的本科生加入課題組！

地址：桂林理工大學(xué)雁山校區(qū)9棟504室，郵箱（優(yōu)先）：LSQ030080@126.com，電話(huà)：19907736780